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| Figure 5: Microstructure of hemicordierite extruded into pyrophyllite |
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| Figure 6: Microstructure of clay-based hemicordie bricks |
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| Figure 5: Microstructure of hemicordierite extruded into pyrophyllite |
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| Figure 6: Microstructure of clay-based hemicordie bricks |
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| Refractory Castables in Various Parts of CFB Circulating Fluidized Bed Boilers |
Aluminum-chrome bricks containing chromium slag. The aluminum-chrome bricks with an aluminum-chrome slag addition amount (wt) of 30% were used as reference samples, and the formula was set as the basic formula. On this basis, 1wt%, 2wt%, 3wt%, and 4wt% of α-Al2O3 were added respectively, and the increased amount replaced the brown corundum fine powder, keeping the Cr2O3 content unchanged, and exploring the effect of α-Al2O3 on the performance of aluminum-chrome bricks containing chromium slag.
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| Performance of Aluminum-Chrome Bricks |
After the raw aggregates were dry-mixed in a small wet mill for 3 minutes, about 3% of the binder (aluminum dihydrogen phosphate solution) was added. After mixing for 1 minute, the machine was stopped, and fine powder was added to continue mixing. Continue to add binder until the mud is suitable, and the total amount of binder added is about 3.5%. After fully mixing, the material is discharged and loaded into a woven bag lined with a plastic bag. Then the trapped material was sealed for 12 hours and formed on a 630-ton electric press. The molded blank sample is a standard brick (230×114×65mm). The formed wet bricks enter the tunnel drying kiln and are kept warm and dried at 110℃~120℃ (>12 hours). After drying, they are loaded with the loading method with the width direction as the pressure direction. They are heat treated in a 111m long ultra-high temperature tunnel kiln fueled by natural gas. The firing system is 1600℃×4.5h.
According to relevant standards, the bulk density, apparent porosity, compressive strength, linear change rate after firing, load softening temperature and thermal shock stability (1100℃ water cooling) of the samples are tested, and the performance indicators of each experimental brick are tested.
The effect of α-Al2O3 micropowder addition (wt.%) on the volume density, apparent porosity, compressive strength and post-firing linear change rate of aluminum-chrome bricks containing aluminum-chrome slag. With the increase of α-Al2O3 micropowder addition, the apparent porosity decreased, the volume density increased, but the amplitude was not large; the compressive strength tended to increase, but the amplitude was not large. The post-firing linear change rate is gradually decreasing, and the comprehensive effect is better when the α-Al2O3 micropowder is added at 3wt%. This is because the basic mechanism of micropowder is ST filling. Appropriate micropowder is filled in the micropores of refractory aggregate and fine powder, which can increase its volume density and reduce apparent porosity. In corundum products, adding α-Al2O3 micropowder can promote sintering and reduce the sintering temperature.
Since the brown corundum and aluminum-chromium slag used in the raw materials are both electro-melting materials, and the South African chromium ore are both raw materials with high volume density and low apparent porosity, the change rate of the product during the sintering process is very limited. Although the addition of α-Al2O3 micropowder has a certain improvement on the conventional performance, the impact is relatively small. When the addition amount is 3wt%, the filling effect is more obvious, and the performance will be reduced if the addition amount is further increased. This has a certain relationship with the overall particle grading of the product.
Effect of α-Al2O3 on load softening temperature. The addition amount of α-Al2O3 micropowder has almost no effect on the load softening temperature, which is due to the high grade of the raw materials of the product itself. The load softening temperature of the reference sample itself is ≥1700℃. The addition of α-Al2O3 micropowder has the effect of promoting sintering. After sintering, it mainly forms high-melting-point mineral phases such as corundum or aluminum-chromium solid solution. Therefore, it will not reduce the load softening temperature of the product.
Effect of α-Al2O3 addition amount (wt.%) on thermal shock stability As the amount of α-Al2O3 powder added increases, the thermal shock stability of the product is not greatly affected. However, when the amount added is 4wt%, the thermal shock stability decreases. This is because as the volume density of the product increases, the apparent porosity decreases, and the denser structure reduces the thermal shock stability of the product. Therefore, it is more appropriate to add α-Al2O3 powder within 3wt%.
Corundum refractory products, Al2O3 98% or more, self-bonded solid phase sintered high-purity corundum brick products, the bonding phase is mainly corundum, and there is a small amount of mullite, etc. Mainly used in petrochemical industry gasification furnace, carbon black reactor, gasification furnace, ammonia decomposition furnace, two-stage reforming furnace, high temperature and ultra-high temperature kiln in refractory ceramic industry, blast furnace in metallurgical industry, etc.
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| Rongsheng Corundum Bricks |
①Low creep high alumina bricks: For high alumina bricks with a creep temperature of 1500℃-1550℃, adding some fused corundum and silica raw materials can produce low creep rate high alumina bricks.
②Phosphate bonded high alumina bricks: Special-grade or first-grade high alumina bauxite clinker is used as the main raw material, and phosphoric acid solution or aluminum phosphate solution is used as the binder. A small amount of fused corundum, mullite, etc. is added to strengthen the matrix. Chemically bonded refractory products made by heat treatment at 400-600℃. Mainly used in ironmaking hot blast furnaces, cement kilns, electric furnace tops, ladles, etc.
Use fused white corundum, plate-shaped corundum, fused mullite and other raw materials. After batching, mixing, high-pressure molding, and firing in a high-temperature kiln. The main crystal phase of corundum mullite brick products is corundum, and the bonding phase is mullite. Corundum mullite bricks are mainly used in high-temperature firing kilns and kiln tools such as push plates and firing plates in the ceramic industry.
Plate-shaped corundum mullite brick is made of plate-shaped corundum as the main raw material and mullite as the auxiliary raw material. It is made by adding appropriate amounts of high-purity alumina, ultrafine silicon oxide powder and additives. It is strongly pressed and formed by a 300t friction press and fired at high temperature in an oxidizing atmosphere. Plate-shaped corundum mullite brick can be used for a long time in a high temperature environment of 1700 degrees. Characteristics of plate-shaped corundum mullite brick:
(1) The Al2O3 of plate-shaped corundum mullite brick is ≥82%, which has good high temperature resistance, high refractory temperature, and load softening temperature as high as 1700 degrees.
(2) Resistant to chemical erosion, with strong resistance to acidic solutions or slag.
(3) The Fe2O3 content in plate-shaped corundum mullite brick is ≤0.5%, which is resistant to oxidation. It is not easy to react chemically with gases such as O2, H2, and CO.
(4) Good thermal stability, high temperature volume stability, and not easy to expand or shrink.
(5) Good thermal shock resistance, 1100℃ water cooling ≥30 times, resistant to rapid cooling and heating, not easy to peel off.
(6) High compressive strength at room temperature, ≥ 85 MPa, not easy to wear during transportation or unloading.
Physical and chemical indicators of plate-shaped corundum mullite bricks
Project indicators Al2O3, %≥82Fe2O3, %≤0.5Load softening temperature, ℃1700 (0 deformation) Thermal shock stability, times, 1100℃ water cooling ≥30 Normal temperature compressive strength, MPa≥85 Creep rate, %, 1450℃×50h-0.05 High temperature flexural strength, MPa, 1450℃×0.5h≥10
Application of plate-shaped corundum mullite bricks
Plate-shaped corundum mullite bricks can directly contact flames, resist peeling, and resist high temperatures. It can be used as the thermal insulation lining of high-temperature industrial furnaces and as the working layer of other industrial high-temperature kilns. It is mainly used in petrochemical industry, large and medium-sized synthetic ammonia gasification furnaces and magnetic material gas furnace materials, high-temperature industrial kiln supporting facilities materials, etc. Rongsheng Refractory can customize refractory bricks and products of various materials and shapes according to the customer's high-temperature equipment requirements.
Rongsheng Refractory Manufacturer, solutions for high temperature industrial furnace lining refractory materials. Advantages and disadvantages of silicon carbide refractory castables. In the field of amorphous refractory materials, silicon carbide refractory castables have always been a product that has attracted much attention. Whether from raw materials to research and development, or from production to use, it is a product that users love and hate. Understanding the advantages, disadvantages and why silicon carbide refractory castables can resist slag erosion can help companies make better choices.
The biggest advantage of silicon carbide refractory castable is that it has high thermal conductivity, low thermal expansion, and does not react with slag. It has been used in kiln parts with severe slag reaction and high-temperature spalling since a long time ago.
| Rongsheng Silicon Carbide Refractory Castables |
The biggest disadvantage is that the chemical properties are very unstable in certain atmospheres. It is easily corroded in oxidizing gases such as (oxygen, water vapor, carbon monoxide, carbon dioxide), iron oxide, etc., and easily oxidized and decomposed in molten iron and vacuum. Another disadvantage is that silicon carbide refractory castables have poor water solubility. In water-based amorphous refractory materials such as castables, the poor fluidity sometimes causes the poor density of silicon carbide refractory castables. The third disadvantage is the lack of sintering and difficulty in obtaining high strength, but sometimes it is difficult to produce over-sintering and shrinkage, which is a strength in amorphous refractory materials.
When considering the slag resistance and slag resistance of silicon carbide refractory castable, the following aspects must be considered comprehensively: (1) wettability to slag (contact angle) (2) slag invasion (3) reactivity with slag (4) melting point and viscosity of reaction products. Considering these four aspects, although alumina refractory materials are materials that easily react with slag, as raw materials of refractory materials, they are not materials with poor slag resistance. This is because there are not many low-melting point compounds generated by reaction with slag.
The reason why silicon carbide refractory castable is difficult to be wetted by slag is because of the material of silicon carbide itself. SiC has two crystal forms, α and β, and the crystal structure of β-SiC. Among them, α-SiC has about 120 polymorphs such as 4H, 15R and 6H, among which 6H polymorph is the most widely used in industry. In 6H-SiC, Si and C are stacked alternately in layers, the distance between Si layers or C layers is 2.5Å, and the atomic distance between Si-C is about 1.9Å. There is a certain thermal stability relationship between the various forms of SiC, and the α β crystal forms also transform into each other. When the temperature is below 1600℃, SiC exists in the form of β-SiC. When the temperature is higher than 1600℃, β-SiC slowly transforms into various deformation forms of α-SiC (4H, 15R, 6H, etc.) by recrystallization. For α-β transformation, higher pressure is required, while for β-α transformation, only lower pressure is required. The transformation between various types of silicon carbide does not produce volume effect. SiC is a compound with strong covalent bonds. It still maintains high bonding strength at high temperatures, so SiC has high hardness, large elastic modulus, excellent wear resistance, and will not be corroded by most acid and alkali solutions. For the intrusion of slag and the melting point generated after reaction with slag, when compared with oxides, the slag resistance is significantly better.
When using silicon carbide refractory castables in monolithic refractory materials, the advantages, disadvantages, and prices of use should be considered. Only after the use site is determined can the lining material be used more accurately. However, in the actual use environment of monolithic refractory castables, these favorable and unfavorable environments for silicon carbide are mostly mixed. The evaluation of many environments currently used is often inconsistent with the actual use environment.
Lightweight high-strength castable is a new type of refractory material newly developed by Rongsheng Refractory Material Manufacturer. Rongsheng Lightweight High-Strength Thermal Insulation Castable combines the advantages of lightweight materials and high-strength characteristics and is widely used in high-temperature industrial equipment. This material not only has good thermal insulation performance but also is comparable to heavy refractory bricks in strength. Contact Rongsheng for more information.
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| Lightweight High-Strength Insulation Castable |
Lightweight high-strength castables are composed of refractory aggregates (such as lightweight particles), binders, and additives (such as reinforcing materials). Its main characteristics include:
(1) Thermal insulation performance
Reduced heat loss: The lightweight aggregate of lightweight high-strength castables makes it have lower thermal conductivity, which can effectively reduce the conduction and loss of heat. This is of great significance for equipment that needs to maintain high temperatures for a long time (such as blast furnaces, hot blast furnaces, smelting furnaces, etc.), and can reduce energy consumption.
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| Lightweight High-Strength Castables |
Improved temperature control: Good thermal insulation effect makes the temperature distribution in the equipment more uniform, avoids excessive temperature fluctuations, and reduces the occurrence of thermal shock.
(2) High strength
Withstand greater mechanical stress: The high-strength design enables lightweight high-strength castables to withstand greater mechanical stress and impact, especially in some areas affected by high temperature and pressure (such as the inner wall of the furnace, the bottom of the furnace, etc.), and can maintain stability.
Comparable to heavy refractory bricks: Traditional heavy refractory bricks have higher strength, but are often heavier and are not suitable for occasions where a lower dead weight is required. The strength of lightweight high-strength castables has been optimized to be comparable to that of heavy refractory bricks, while having a lower density.
(3) Convenient construction
Quick forming: Castables are constructed by pouring, vibrating or spraying, which is particularly suitable for irregular shapes and difficult-to-brick parts. This construction method not only saves time and manpower, but also avoids the existence of bricklaying joints during the construction process, improving the construction quality.
Adaptable to complex structures: Since the material is in a cast state, it is suitable for use in furnace bodies, furnace walls, furnace bottoms and other parts with complex shapes or difficult to cut and splice.
(4) Good thermal shock resistance
Lightweight and high-strength castables can better adapt to working environments with large temperature fluctuations due to the structural characteristics of their lightweight aggregates, avoiding thermal stress and cracks caused by drastic temperature changes. This enables it to effectively improve durability and stability in equipment such as hot blast furnaces and blast furnaces.
(5) Energy saving and maintenance reduction
Due to its excellent thermal insulation performance, lightweight high-strength castables help improve the energy efficiency of the equipment. It reduces energy waste and enables equipment to operate at a higher thermal efficiency, reducing operating costs.
Its good thermal shock resistance, high-temperature resistance, and strength also extend the service life of the refractory lining, thereby reducing the frequency of maintenance and replacement and reducing overall operating costs.
Rongsheng's lightweight high-strength castable is a refractory material that combines light weight, high strength, excellent thermal insulation and thermal shock resistance. It can provide good performance in high-temperature metallurgical equipment. Compared with traditional refractory bricks, it can provide similar or even stronger strength. And due to its lightweight structure, it has better thermal isolation effect, helping to improve the energy efficiency of equipment and reduce repair and maintenance costs. It is especially suitable for metallurgical equipment that requires high strength, good thermal insulation and high temperature resistance and thermal shock resistance. Such as blast furnaces, hot blast furnaces, coke ovens, steelmaking furnaces, etc.
The quality requirements of the checker bricks in the heat storage chamber are mainly as follows:
1. In order to reduce the friction resistance of the gas flowing in the checker bricks and make the resistance in each heat storage chamber consistent, it is convenient to master the heating system, and the holes of the upper and lower layers of the checker bricks are required to be aligned as much as possible.
2. Keep the checker bricks clean to avoid blockage of the brick holes and reduce the number of cleaning times during production to improve heating efficiency.
3. The bricklayer should be laid smoothly and have a good staggered width.
4. Maintain necessary expansion joints. The gas flow space at the top of the heat storage chamber should maintain a certain cross-sectional area according to the design to prevent vortexes from being generated when the gas is distributed at the top of the heat storage chamber.
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| Rongsheng Checker Bricks |
Rongsheng Refractory Manufacturer, Regenerator Checker Brick, Magnesia Checker Brick. Contact Rongsheng for more information.
Construction of checker bricks
The laying time of checker bricks is divided into two construction methods according to the width of the regenerator: laying at the same time as the regenerator furnace wall (first laying) and laying after the entire furnace body is built and cleaned (latter laying). According to construction experience, when the net width of the regenerator is less than 310 mm (such as Otto coke oven), the construction method of laying checker bricks first should generally be adopted. This is because it is more difficult to lay checker bricks later in a narrow regenerator.
The construction method of laying checker bricks first has several advantages: First, because the workers are standing on the wall of the regenerator to lay checker bricks, the operating conditions are better, and it is easy to check after laying. Therefore, it can ensure that each checker brick hole is connected from top to bottom and has good staggered joints. However, due to the addition of many processes - cleaning protection and cleaning work, the construction progress is slow and it is more difficult to ensure cleaning.
The construction method of laying checker bricks is as follows: checker bricks can be laid in sections, that is, according to the convenience of construction, they can be laid in two sections on the entire height of the heat storage chamber, that is, divided into upper and lower sections according to the height of the replacement handrail. After the first section of the main wall is built, all the cleaning and brick joint finishing work on the wall surface is completed, and the grate bricks are cleaned, and the row numbers of the grate bricks are checked once, and then the first layer of checker bricks is placed on the grate foot platform according to the designed position, and the expansion joints on the four sides and the staggered joint width between the checker bricks and the grate foot platform are checked. Make sure that the checker bricks can be firmly placed on the grate foot platform, and finally lay each layer of checker bricks from the center partition wall to both sides according to the designed position.
During construction, the checker bricks are placed on the brick pad. The hook of the checker brick is inserted into the hole of the checker brick to place the checker brick in the heat storage chamber. Then use a long wooden stick to adjust its position. When storing, it can be laid from the center to the furnace head in a stepped shape, or it can be laid layer by layer. The heat storage chamber sealing wall is built after the checker bricks of this section are laid.
After the first section of checker bricks is laid, the checker bricks are covered with a checker brick protection board to prevent waste such as mortar from falling into the checker bricks. Then continue to build the heat storage chamber wall. When it reaches the top of the heat storage chamber, lay the second section of checker bricks and build the second section of sealing wall.
Cordierite brick s and kiln furniture: Cordierite bricks are a type of refractory material with cordierite (2MgO·2Al2O3·5SiO2) as its main c...