Rongsheng Refractory Manufacturer, solutions for high temperature industrial furnace lining refractory materials. Advantages and disadvantages of silicon carbide refractory castables. In the field of amorphous refractory materials, silicon carbide refractory castables have always been a product that has attracted much attention. Whether from raw materials to research and development, or from production to use, it is a product that users love and hate. Understanding the advantages, disadvantages and why silicon carbide refractory castables can resist slag erosion can help companies make better choices.
Advantages and disadvantages of silicon carbide refractory castable products
The biggest advantage of silicon carbide refractory castable is that it has high thermal conductivity, low thermal expansion, and does not react with slag. It has been used in kiln parts with severe slag reaction and high-temperature spalling since a long time ago.
![]() |
Rongsheng Silicon Carbide Refractory Castables |
The biggest disadvantage is that the chemical properties are very unstable in certain atmospheres. It is easily corroded in oxidizing gases such as (oxygen, water vapor, carbon monoxide, carbon dioxide), iron oxide, etc., and easily oxidized and decomposed in molten iron and vacuum. Another disadvantage is that silicon carbide refractory castables have poor water solubility. In water-based amorphous refractory materials such as castables, the poor fluidity sometimes causes the poor density of silicon carbide refractory castables. The third disadvantage is the lack of sintering and difficulty in obtaining high strength, but sometimes it is difficult to produce over-sintering and shrinkage, which is a strength in amorphous refractory materials.
Why is silicon carbide refractory castable resistant to slag erosion?
When considering the slag resistance and slag resistance of silicon carbide refractory castable, the following aspects must be considered comprehensively: (1) wettability to slag (contact angle) (2) slag invasion (3) reactivity with slag (4) melting point and viscosity of reaction products. Considering these four aspects, although alumina refractory materials are materials that easily react with slag, as raw materials of refractory materials, they are not materials with poor slag resistance. This is because there are not many low-melting point compounds generated by reaction with slag.
The reason why silicon carbide refractory castable is difficult to be wetted by slag is because of the material of silicon carbide itself. SiC has two crystal forms, α and β, and the crystal structure of β-SiC. Among them, α-SiC has about 120 polymorphs such as 4H, 15R and 6H, among which 6H polymorph is the most widely used in industry. In 6H-SiC, Si and C are stacked alternately in layers, the distance between Si layers or C layers is 2.5Å, and the atomic distance between Si-C is about 1.9Å. There is a certain thermal stability relationship between the various forms of SiC, and the α β crystal forms also transform into each other. When the temperature is below 1600℃, SiC exists in the form of β-SiC. When the temperature is higher than 1600℃, β-SiC slowly transforms into various deformation forms of α-SiC (4H, 15R, 6H, etc.) by recrystallization. For α-β transformation, higher pressure is required, while for β-α transformation, only lower pressure is required. The transformation between various types of silicon carbide does not produce volume effect. SiC is a compound with strong covalent bonds. It still maintains high bonding strength at high temperatures, so SiC has high hardness, large elastic modulus, excellent wear resistance, and will not be corroded by most acid and alkali solutions. For the intrusion of slag and the melting point generated after reaction with slag, when compared with oxides, the slag resistance is significantly better.
When using silicon carbide refractory castables in monolithic refractory materials, the advantages, disadvantages, and prices of use should be considered. Only after the use site is determined can the lining material be used more accurately. However, in the actual use environment of monolithic refractory castables, these favorable and unfavorable environments for silicon carbide are mostly mixed. The evaluation of many environments currently used is often inconsistent with the actual use environment.